PLASMA SHEATHS
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Lack of electrons close to anode (almost all electrons are swollen very fast by the positive anode)
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Lack of energetic electrons close to cathode (electrons are rejected/slowed down by the negative cathode)
Consequently, there are less ionization/excitation processes close to the cathode and anode. Therefore, due to the lack of photons, dark sheaths will be present close to the anode and cathode in a DC plasma (constant voltage applied on anode).