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Thermal growth tutorial

Modules

1. Oxidation

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CHEMICAL REACTIONS that take place:

  • Si(s) + O2(g) → SiO2(s)  dry oxidation
  • Si(s) + H2O(g) → SiO2(s) + H2(g)  wet oxidation (a nonreactive gas is passed through water at high temperature and water vapour is transported this way in the reactor)

  • Silicon oxidises at room temperature, forming native oxide (thin layer of a few nanometers)
  • The higher temperature (700-1000oC) is needed so that the oxygen atoms diffuse through the formed oxide thicker layers, in order to reach the silicon surface and react
  • Diffusion constant of O is higher than diffusion constant of Si a reaction takes place at SiO2/Si interface

1. Oxidation

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